THE PALLADIUM COMPLEX-CATALYZED REACTIONS OF HEXAORGANODISILANES WITH DIENES
نویسندگان
چکیده
منابع مشابه
Enantioselective desymmetrizing palladium catalyzed carbonylation reactions: the catalytic asymmetric synthesis of quaternary carbon center containing 1,3-dienes.
A desymmetrization protocol has been used to develop a palladium catalyzed enantioselective carbonylation process. Achiral cyclic bis-alkenyltriflates are converted to their corresponding monoester derivatives with selectivities of up to 96% ee.
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Palladium (II) coordination complexes catalyze the reaction of alcohols with ketones to yield ethers. During the catalytic cycle, the alcohol adds selectively to the β-carbon (anti-Markovnikov). In this work, mechanism and kinetics for the reaction of methanol with methyl vinyl ketone (MVK), being catalyzed by Pd, has been theoretically investigated in detail. Using quantum mechanical approach,...
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Palladium (II) coordination complexes catalyze the reaction of alcohols with ketones to yield ethers. During the catalytic cycle, the alcohol adds selectively to the β-carbon (anti-Markovnikov). In this work, mechanism and kinetics for the reaction of methanol with methyl vinyl ketone (MVK), being catalyzed by Pd, has been theoretically investigated in detail. Using quantum mechanical approach,...
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A series of [M (R2PC2H4PR:)(butadiene)] com plexes of Ni, Pd and Pt has been prepared and their structures investigated NMR-spectroscopically. The nickel and palladium com plexes, irre spective of the substituents at phosphorus, contain a fluxional ?/2-bonded butadiene m olecule. In the case of platinum the bonding mode is ligand dependent: an ^-arrangem ent is observed where R is tert-butyl o...
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ژورنال
عنوان ژورنال: Chemistry Letters
سال: 1975
ISSN: 0366-7022,1348-0715
DOI: 10.1246/cl.1975.887